Parameter Corrections and Differences
Cu-Zr system
[2006He ] Parameters taken from [1994Zen], except for the CuZr phase. G(CU1ZR1,CU:ZR;0)=-10052.12-3.81598*T [1994Zen] G(CU1ZR1,CU:ZR;0)=-10152.12-3.73320*T [2006He ] Intermetallic phases involved: Cu5Zr, Cu51Zr14, Cu8Zr3, Cu10Zr7, CuZr, CuZr2. [2006Wan] Re-assessment of this system. Intermetallic pahses involved: Cu9Zr2, Cu51Zr14, Cu8Zr3, Cu24Zr13, Cu2Zr, Cu10Zr7, CuZr, Cu5Zr8, CuZr2-h, CuZr2-l. [2006Abe] Parameters for solid phases are taken from [2003Zai]. The liquid is described by Associated solution model with a Cu2Zr associate. The glass transition is modeld by "Magnetic model" [2000Sha]. Parameter for the CuZr2 in [2003Zai] was slightly modified to G(CU1ZR2,CU:ZR;0)=-19797+6.68*T+DG DG=2660-2.29*T FCC and HCP solid solutions are described as an ideal solution. Intermetallic phases involved: Cu9Zr2, Cu51Zr14, Cu8Zr3, Cu5Zr8, Cu2Zr, Cu10Zr7, CuZr, CuZr2. Kauzmann paradox occurs below about 200K. See Fig.5 in [2006Abe]. [1994Zen] Intermetallic phases involved: Cu5Zr, Cu51Zr14, Cu8Zr3, Cu10Zr7, CuZr, CuZr2. [1985Sau] The glass transition "a mangentic model [2000Sha]" is added in the TDB/TCM file. The Lattice stabilities are taken from [Kaufman] and SGTE-Pure database. There seems to be small difference between them. Intermetallic phases involved: Cu5Zr, Cu51Zr14, Cu8Zr3, Cu10Zr7, CuZr, CuZr2 Close
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